Seven Days to the Execution 1956
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A woman is murdered. The police has arrested her husband, but the evidence show that he was seen somewhere else at the time of the murder. The witnesses refuse to testify, but are convinced to do so, only to get murdered one by one. The accuser is finally sentenced to death. On the day of the execution, when they're taking the man to the prison for execution, the real murderer shows up and gets arrested.